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Novel technology to produce ferromanganese alloy from ...

Therefore, steelmaking slag can be considered as a Mn resource. Although ferromanganese alloys can be produced by the reduction of steelmaking slag, P content in the product is too high and Mn content is too low, preventing the use of these alloys for the steelmaking process. The separation of P from Mn and increase in the Mn/Fe ratio is ...

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Extraction and separation of manganese and iron from ...

 · Judging from the extraction of Fe and Mn from a secondary resource (The leaching residue from desulfurization and denitrification of exhaust gas treatment process with manganese ore as absorbent) including pyrolusite and goethite with a low Mn content (30.1%Fe and 4.0%Mn) (Deng et al., 2018), as well as manganese ores with a low Fe content ...

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(PDF) Recovery of manganese as ferro-silico …

[Show full abstract] the optimal choice of raw materials mix and optimum conditions controlling the production process, such as smelting time, basicity, coke ratio, Mn/Fe and Mn/Si ratios of the ...

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Application Example: Using the Process Metallurgy …

and other slag components to metallic Fe, Mn, and Si. The resulting liquid metal droplets sink through the slag and combine with the liquid steel. This process of phase transfer is outlined in Figure 4. Figure 4 Schematic of the kinetic model for material additions resulting in the formation of new

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Characterization of Manganese Alloy Residues for the ...

 · However the contents of Mn, Fe, Si and P in the fraction below 1.18 mm did not meet the chemical specifications for commercial manganese alloys, except for phosphorous. Optical microscopy of the fraction below 1.18 mm, showed that 87.95% of the FeSiMn corresponded to the alloy and that the slag content was 12.05%. For the HC-FeMn sample, 95.07%

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Slag corrosion mechanism of lightweight Al2O3–MgO …

 · With P(O 2) = 0.21 atm, Mn and Fe in slag were present in the form of divalent and/or trivalent cations and were incorporated into spinel to form MnFe 2 O 4 solutions and MgAl 2 O 4 solutions during the corrosion process. Since Fe, Mn ions were largely consumed, liquid with high viscosity formed and the continuing infiltration was suppressed.

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Recovery and separation of Fe and Mn from simulated ...

Tailings from the vanadium extraction process are discarded each year as waste, which contain approximately 30wt% of Fe. In our previous work, we extracted Fe and Mn from vanadium slag, and Fe and Mn existed in the form of FeCl 2 and MnCl 2 after chlorination by NH 4 Cl to achieve effective and green usage of waste containing Fe and Mn.

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Adsorptive Removal of Manganese from Manganese Slag ...

With the increasing Fe content (2.58-5.07%) in biochar, the BET surface area of the Citric Acid-Fe biochar composites decreased from 81 m2/g to 35 m2/g, while the EDTA-Fe biochar composites decreased from 96 m2/g to 22 m2/g. The fixed loaded Fe biochars mixtures had a reduction of 4.02% to 32.01% in Mn sorption contrasting with raw biochar.

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An Environment-Friendly Process Featuring Calcified ...

 · CaO. The content of V2O5 in residues after vanadium extraction was lower than 1.2 wt.%, while other valuable metals like Fe, Mn, Cr and Ti were concentrated. With no alkaline metal salts added in this process, the metal resources of Fe, Mn, Cr and Ti in the residues were more feasible to be recovered with pyrometallurgy processes.

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Recovery and separation of Fe and Mn from simulated ...

 · Tailings from the vanadium extraction process are discarded each year as waste, which contain approximately 30wt% of Fe. In our previous work, we extracted Fe and Mn from vanadium slag, and Fe and Mn existed in the form of FeCl 2 and MnCl 2 after chlorination by NH 4 Cl to achieve effective and green usage of waste containing Fe and Mn. In this work, square wave voltammetry (SWV) and …

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A Brief Summary of Zinc Oxide Processing Methods …

 · Report by: Noël Masson, Pascal Briol, PBSIM & BFS Consulting Engineering 2 of 11 Waelz Technology Developed by German firms at the beginning of 20th century, with the first operating plant in 1925. The material containing zinc (oxide, silicate, carbonate, zinc ferrite) must be pelletized with a carbon reductant.

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A novel conversion process for waste slag: …

The main components of blast furnace slag (BFS) are CaO, SiO 2, A1 2 O 3, MgO and slight amounts of transition metals such as Fe, Ti and Mn.We successfully synthesized a hydrotalcite-like compound from BFS via a convenient chemical process: acid …

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Silico- Manganese – IspatGuru

 · Silico-manganese (Si-Mn) is a metallic ferro alloy which is being used to add both silicon (Si) and manganese (Mn) as ladle addition during steelmaking. Because of its lower carbon (C) content, it is a preferred ladle addition material during making of low carbon steels. Si-Mn is a ferroalloy composed principally of Mn, Si, and Fe (iron), and ...

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An Environment-Friendly Process Featuring Calcified ...

 · The content of V 2 O 5 in residues after vanadium extraction was lower than 1.2 wt.%, while other valuable metals like Fe, Mn, Cr and Ti were concentrated. With no alkaline metal salts added in this process, the metal resources of Fe, Mn, Cr and Ti in the residues were more feasible to be recovered with pyrometallurgy processes.

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Thermochemical analysis for the reduction behavior of FeO ...

 · This indicates that both Mn and Fe could be recovered from EAF slag by means of the ASR process. The content of Al 2 O 3 in molten slag continuously increased with increasing added Al. Because the absolute amount of slag decreased due to the reduction of FeO and MnO, the relative content of CaO in the molten slag was enriched.

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Thermochemical analysis for the reduction behavior of FeO ...

 · 1. Introduction. Following Part I of the present series, which included experimental investigations of the reaction between FeO in EAF slags and Al at 1773 K and which emphasized the quantitative determination of iron recovery and reduction behavior, the present study describes the behavior of oxides in EAF slag and the effects of the slag's thermophysical properties on Fe (and Mn) …

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Novel Understanding of Simultaneous Extraction of ...

 · During the roasting process, V 3+ in VS and Mn 4+ in LGP were initially oxidized and reduced to form Fe 0.07 V 1.93 O 4 (V 4+) and Mn 2 O 3 (Mn 3+) until it reached a temperature of 670 °C. After reaching 670 °C, Mn 3+ in LGP gradually oxidized V 4+ and further separated vanadium from iron to form acid-soluble manganese vanadate, by which Mn 3+ was reduced further as Mn 2+ .

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(PDF) Metallothermic reduction of manganese …

Al 2 O 3.SiO 2 in the slag phase, in addition to Fe, Mn ... via the aluminothermic process. Moreover, as the Al content in the charge was high, it also completely reduced SiO2 in the industrial ...

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Manganese Ore - an overview | ScienceDirect Topics

Rauf Hurman Eric, in Treatise on Process Metallurgy: Industrial Processes, 2014. 1.10.4.6.3 Raw Materials Required for the Manufacture of High-Carbon Ferromanganese. Manganese ores from different sources vary widely in their contents of manganese, iron, silica, alumina, lime, magnesia, and phosphorous. To produce standard ferromanganese (78% Mn) and a slag containing 30% MnO, the …

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(PDF) Recovery of manganese as ferro-silico …

[Show full abstract] the optimal choice of raw materials mix and optimum conditions controlling the production process, such as smelting time, basicity, coke ratio, Mn/Fe …

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Influence of Slag Basicity and Temperature on Fe and Mn ...

We have proposed a novel process for recycling Mn wasted in steelmaking slag via sulfurization to separate P from Mn. For clarifying the efficient recovery of Mn from steelmaking slag, the influences of slag basicity and temperature on the distributions of Mn and Fe between the Fe–Mn–Ca–O–S matte and FeO–MnO–MgO–P 2 O 5 –SiO 2 –CaO slag were investigated.

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Silicomanganese production from manganese rich slag ...

 · Manganese recovery from this slag in the form of manganese ferroalloys compensates for the excess cost of the treatment process. Manganese rich slags produced from the injection of high manganese pig iron under at optimum conditions have levels of (Mn)>35 wt-%, (Mn)/(Fe)>7.65, (Mn)/(Si)>2 and (Mn)/(P)>285, which satisfy requirements for use as ...

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An Improved Process for the Production of Low-Carbon ...

 · The thermodynamic equilibrium calculations helped to understand the overall process chemistry in the Mn 2 O 3-Fe 2 O 3-SiO 2-Al 2 O 3 slag system. The lime content in the charge mix played an essential role during reduction of MnO by SiMn. The suitable CaO/SiO 2 ratio in the charge mix was to be 1.5–1.77 by thermochemical simulation studies ...

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Carbide Capacity of CaO–SiO2–MnO Slag for the …

Manganese rich slag is generated from the high carbon ferromanganese (HC FeMn) production process. This slag generally contains 30 to 40mass% M,2) In addition to its high manganese content, it also has the advantage of high Mn/Fe ratio, low phosphorus content, low fine content and low cost.3) The possibility of using such a slag for the

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Lecture 28: Materials Balance in Iron making Key words ...

 · Fe balance: (0.995).(Fein iron ore) =Fe in pig iron Let x kg iron ore 0.995 H 5 5 6 5 : 4 H0.78 H L927 L Ú à Ù ß ï (a) Weight of slag: Slag consists of FeO,SiO 6,Al 6 O 7,MgO,P 6 O 9,CaO Si in slag L Si in ore ESi in coke ESi in limestone LSi in pig iron

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Silicomanganese Production – Process Understanding

 · A process temperature of 1600 to 1650°C is necessary to obtain metal with sufficiently high content of Si and discard slag with low MnO. FeMn slag has a relatively low melting temperature (about 1250°C) compared with Mn-ores. Accordingly, a high share of FeMn slag will tend to give lower process temperatures[1]. When the Mn-ore starts melting ...

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Ferro-Manganese – IspatGuru

 · Fe-Mn is an important additive used as a deoxidizer in the production of steel. It is a master alloy of Fe and Mn with a minimum Mn content of 65 %, and maximum Mn content of 95 %. There are two families of Mn alloys. One is called Fe …

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